Benzylidene Schiff Base Corrosion Inhibition and Electrochemical Studies of Mild Steel in 1M HCI and 0.5M H2SO4 Acidic Solutions

نویسندگان

چکیده

N ̶ Benzylidene 4 Methoxyaniline (NB4MA) schiff base was synthesized and investigated corrosion behavior of mild steel (MS) in 1M HCI 0.5M H2SO4. The efficiency studied by means mass loss electrochemical techniques. studies confirm that Ecorr displacement about 32mV confirms anodic cathodic type inhibitor. positive direction potential curves confirmed adsorption on metal surface. Langmuir isotherm observed. Electrochemical impedance (EIS) exposed inhibition effectiveness enlarged with even increasing concentration Schiff found capacity 90 – 95%. Furthermore, thermodynamic parameters were which elaborates ΔG0ads parameter since favorable interaction between inhibitor causes efficient adsorption. morphology revealed has strong affinity to adhere improve against acidic media. quantum chemical also electrons distribution base.

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Branched Polymers and their Application in Corrosion Inhibition for Mild Steel in 1M H2SO4 Medium

The adsorption and corrosion inhibiting effect of branched polymers (BATP, BAAZ, BETP & BEAZ) on mild steel in 1M H2SO4 at 30±1°C was investigated using gravimetric, electrochemical impedance spectroscopy (EIS), and potentiodynamic polarization techniques. The experimental findings revealed that BATP inhibited the corrosion reaction in the acid environment to greater extend compared to BAAZ, BE...

متن کامل

Effect of piperidones on hydrogen permeation and corrosion inhibition of mild steel in acidic solutions

The influence of 3-methyl-2,6-diphenyl piperidin-4-one (MDPO) and 2phenyl decahydroquinoline-4-one (PDQO) synthesised in the laboratory on hydrogen permeation and corrosion inhibition of mild steel in 1N H2SO4 has been studied using weight loss and various electrochemical AC and DC corrosion-monitoring techniques. Both the compounds inhibit the corrosion of mild steel in H2SO4. Potentiodynamic ...

متن کامل

Inhibition of Mild Steel Corrosion in Sulfuric Acid Solution by New Schiff Base

The efficiency of Schiff base derived from 4-aminoantipyrine, namely 2-(1,5-dimethyl-4-(2-methylbenzylidene)amino)-2-phenyl-1H-pyrazol-3(2H)-ylidene) hydrazinecarbothioamide as a corrosion inhibitor on mild steel in 1.0 M H2SO4 was investigated using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization (PD) and electrochemical frequently modulation (EFM) in addition to the...

متن کامل

INHIBITION OF CORROSION OF CARBON STEEL IN HCl SOLUTIONS BY VARIOUS SCHIFF BASE

Evaluation of corrosion inhibitors for steel in acidic media is important for some industrial facilities as well as is very interesting from theoretical aspects. Most of the effective inhibitors are organic compounds containing nitrogen, phosphorus and sulphur in their structures [1, 2]. Heteroatoms such as nitrogen, oxygen and sulphur are capable of forming coordinate covalent bond with metal ...

متن کامل

Corrosion Inhibition of Mild Steel in Acidic Solution by Apricot Gum as a Green Inhibitor

The inhibitive effect of apricot gum AG on mild steel in 0.5 M phosphoric acid solution was investigated by potentiodynamic polarization, electrochemical impedance spectroscopy EIS, linear polarization resistance and electrochemical noise EN techniques. The inhibition efficiency increased with increasing AG concentration up to a certain value and decreased with increasing temperature. Polarizat...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Oriental journal of chemistry

سال: 2022

ISSN: ['0970-020X', '2231-5039']

DOI: https://doi.org/10.13005/ojc/380512